Abstract
Samples of low- and high-temperature modifications of LiCoO2 were produced and described. The heat capacity was measured by DSC in the temperature ranges of 140–570 and 180–570 K, respectively. The enthalpy and entropy of the cobaltates with respect to temperature were calculated from the data of heat capacity.
Similar content being viewed by others
References
T. Ohzukua and R. J. Brodd, J. Power Source 174, 449 (2007).
E. Antolini, Solid State Ionics 170, 159 (2004).
H. J. Orman and P. J. Wiseman, Acta Crystallogr., Sect. C 40, 12 (1984).
Y. Shao-Horn, S. A. Hackney, A. J. Kahaian, et al., J. Solid State Chem. 168, 60 (2002).
B. Garcia, P. Barboux, F. Ribot, et al., Solid State Ionics 80, 111 (1995).
R. J. Gummow, M. M. Thackeray, W. I. F. David, et al., Mater. Res. Bull. 27, 327 (1992).
C. Wolverton and A. Zunger, Phys. Rev. B 57, 2242 (1998).
M. Ménétrier, D. Carlier, M. Blangero, et al., Electrochem. Solid-State Lett. 11, A179 (2008).
H. Kawaji, M. Takematsu, T. Tojo, et al., J. Thermal Anal. Calorim. 68, 833 (2002).
M. Wang and A. Navrotsky, Solid State Ionics 166, 167 (2004).
H. Yokokawa, N. Sakai, K. Yamaji, et al., Solid State Ionics 113–115, 1 (1998).
Y. C. Zhang, H. Tagawa, and S. Asakura, J. Electrochem. Soc. 144, 4345 (1997).
TOPAS, Vers. 3 (Karlsruhe, Germany, 2005).
ICSD Data Base, Vers. 2006-1 (Karlsruhe, Germany, 2006).
B. K. Marsh, A Thesis Submitted to the Council for National Academic Awards in Partial Fulfilment of the Requirements for the Degree of Doctor of Philosophy (The Hatfield Polytechn., Cement Concrete Assoc., 1984).
L. V. Borisovskikh, G. N. Mazo, and V. M. Ivanov, Vestn. Mosk. Univ., Ser. Khim. 40, 373 (1999).
J. L. Haas and J. R. Fisher, Am. J. Sci. 276, 525 (1976).
M. Antaya, K. Cearns, J. S. Preston, et al., J. Appl. Phys. 1, 2799 (1994).
V. R. Galakhov, V. V. Karelina, D. G. Kellerman, et al., Fiz. Tverd. Tela 44, 257 (2002) [Phys. Solid State 44, 268 (2002)].
K. Nakamura, M. Yamamoto, K. Okamura, et al., Solid State Ionics 121, 301 (1999).
D. G. Kellerman, S. P. Gabuda, N. A. Zhuravlev, et al., Zh. Strukt. Khim. 48, 507 (2007) [J. Struct. Chem. 48, 462 (2007)].
J. Graetz, C. Julien, and R. Jazami, 204th Meeting of the Electrochem. Soc. Orlando, 2003, p. 371.
R. P. Ozerov, Usp. Fiz. Nauk 47, 452 (1952).
M. Yang, Y. Zhong, and Z.-K. Liu, Solid State Ionics 178, 1027 (2007).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © A.L. Emelina, M.A. Bykov, M.L. Kovba, B.M. Senyavin, E.V. Golubina, 2011, published in Zhurnal Fizicheskoi Khimii, 2011, Vol. 85, No. 3, pp. 420–426.
Rights and permissions
About this article
Cite this article
Emelina, A.L., Bykov, M.A., Kovba, M.L. et al. Thermochemical properties of lithium cobaltate. Russ. J. Phys. Chem. 85, 357–363 (2011). https://doi.org/10.1134/S0036024411030071
Received:
Published:
Issue date:
DOI: https://doi.org/10.1134/S0036024411030071


